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Organic Chemistry: 100 Must-Know Mechanisms

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In chemistry, good problem-solving requires a balanced combination of scientific intuition and methodical analysis. Additionally, thoughtfully presented diagrams and infographics can convey a large amount of complex information in a more intuitive and accessible manner. 100 Must-Know Mechanisms (Second Edition) strives to be at the intersection of these two key principles. Its thorough visualizations enable experienced readers to use it as a quick reference for specific mechanisms of interest. At the same time, the book’s breadth of covered reactions, from classic to cutting-edge, make it a good study-aid for the developing chemist. A slow and consistent study of the entire series of mechanisms can help set the foundation for good scientific intuition, while its detailed infographics and careful navigation features encourage coming back to it frequently. This edition includes over 40 new illustrations, numerous new mechanistic schemes, enhanced original figures with a variety of real-case examples, and more. New in this edition: Dot structure added for most mechanisms. Selected mechanisms accompanied by specific examples with step-by-step explanation using Lewis dot structures. Name reactions accompanied by additional detailed mechanisms.

Author(s): Roman A. Valiulin
Edition: 2
Publisher: De Gruyter
Year: 2023

Language: English
Pages: 287
City: Berlin

Cover
Half Title
Also of Interest
Organic Chemistry: 100 Must-Know Mechanisms
Copyright
Dedication
Second Edition
Preface and Overview
Contents
List of Acronyms and Abbreviations
2. Nucleophilic Substitution Mechanism
3. Aromatic Electrophilic Substitution Mechanism
4. Aromatic Nucleophilic Substitution Mechanism
5. Aromatic Radical Nucleophilic Substitution Mechanism
6. Elimination Mechanism
7. Acyloin Condensation
8. Alkyne Zipper Reaction
9. Arbuzov Reaction
10. Arndt–Eistert Synthesis
11. Baeyer–Villiger Oxidation
12. Barton Decarboxylation
13. Baylis–Hillman Reaction
14. Beckmann Rearrangement
15. Benzoin Condensation
16. Benzyne Mechanism
17. Bergman Cyclization
18. Birch Reduction
19. Bischler‒Napieralski Cyclization
20. Brown Hydroboration
21. Buchwald–Hartwig Cross-Coupling
22. Cannizzaro Reaction
23. Chan–Evans–Lam Cross-Coupling
24. Chichibabin Amination
25. Claisen Condensation
26. Claisen Rearrangement
27. Cope Elimination
28. Cope Rearrangement
29. Criegee and Malaprade Oxidation
30. CuAAC
31. Curtius Rearrangement
32. Darzens Condensation
33. Dess–Martin Oxidation
34. Diazotization (Diazonium Salt)
35. Diels–Alder Cycloaddition
36. Di-π-Methane Rearrangement
37. Favorskii Rearrangement
38. Fischer Indole Synthesis
39. Friedel–Crafts Acylation and Alkylation
40. Gabriel Synthesis
41. Gewald Reaction
42. Glaser–Eglinton–Hay Coupling
43. Grignard Reaction
44. Grob Fragmentation
45. Haloform Reaction
46. Heck Cross-Coupling
47. Hell–Volhard–Zelinsky Reaction
48. Hiyama Cross-Coupling
49. Hofmann Elimination
50. Horner–Wadsworth–Emmons Olefination
51. Jones Oxidation
52. Kucherov Reaction
53. Kumada Cross-Coupling
54. Ley–Griffith Oxidation
55. Liebeskind–Srogl Cross-Coupling
56. Mannich Reaction
57. McMurry Coupling Fig.
58. Meerwein–Ponndorf–Verley Reduction
59. Michael Addition
60. Minisci Reaction
61. Mitsunobu Reaction
62. Miyaura Borylation
63. Mukaiyama RedOx Hydration
64. Nazarov Cyclization
65. Nef Reaction
66. Negishi Cross-Coupling
67. Norrish Type I and II Reactions
68. Olefin (Alkene) Metathesis
69. Oppenauer Oxidation
70. Ozonolysis
71. Paal–Knorr Syntheses
72. Paternò–Büchi Reaction
73. Pauson–Khand Reaction
74. Peptide (Amide) Coupling
75. Pictet–Spengler Reaction
76. Pinacol–Pinacolone Rearrangement
77. Polonovski Reaction
78. Prilezhaev Epoxidation
79. Prins Reaction
80. Pummerer Rearrangement
81. Ramberg–Bäcklund Rearrangement
82. Reformatsky Reaction
83. Robinson Annulation
84. Shapiro Reaction
85. Sonogashira Cross-Coupling
86. Staudinger Reaction
87. Steglich Esterification
88. Stille Cross-Coupling
89. Suzuki Cross-Coupling
90. Swern Oxidation
91. Ugi Reaction
92. Ullmann Aryl–Aryl Coupling
93. Upjohn Dihydroxylation
94. Vilsmeier–Haack Reaction
95. Wacker Oxidation
96. Wagner–Meerwein Rearrangement Fi
97. Weinreb Ketone Synthesis
98. Wittig Reaction
99. Wohl–Ziegler Reaction
100. Wolff–Kishner Reduction
Acknowledgments
Bibliography and References