Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications

Cover
Title Page
Copyright
Contents
Preface
Chapter 1 Metallosurfactants, a “Novel Portmanteau”: A Holistic Insight into the Structural–Physiognomies Relationships, Synthesis Stratagems, and Characterization
1.1 Introduction
1.2 Intrinsic Physiognomies of Metallosurfactants
1.3 Classification of Metallosurfactants
1.4 Syntheses Stratagems and Characterization of Metallosurfactants
1.4.1 Metathesis Reaction
1.4.2 Ligand Substitution Reaction
1.4.3 Ligand Insertion Reaction
1.5 Conclusion
References
Chapter 2 Metallosurfactants: A Surface and Interface Perspective
2.1 Introduction
2.2 Micellization and Surface Parameters
2.2.1 Thermodynamics of Micellization
2.2.2 Adsorption Parameters
2.3 Adsorption of Surfactant Monolayers
2.4 Conclusions
References
Chapter 3 Metallosurfactant Self‐Assembly: Structures and Chemistry of Interfacial, Biphasic, and Phase Transfer Catalysis
3.1 Introduction
3.2 Self‐Aggregation Behavior
3.2.1 Micelles
3.2.2 Inverted Micelles
3.2.3 Vesicles
3.2.4 Lamellar Phases
3.3 Chemistry of Catalysis
3.3.1 Micellar Catalysis
3.3.2 Vesicular Structures in Catalysis
3.3.3 Interfacial Catalysis
3.4 Conclusions
Acknowledgment
References
Chapter 4 Hydrolytic Metallosurfactants: Nanocatalysts for Esterolytic Reactions
4.1 Introduction
4.2 Metallosurfactants as Nanocatalyst for Esterolytic Reactions
4.3 Catalytic Hydrolysis of Carboxylate Esters
4.4 Catalytic Hydrolysis of Phosphate Esters
4.5 Quantitative Treatment of Observed Rates: Application of Kinetic Models
4.6 Conclusion
References
Chapter 5 Metallosurfactants as Catalysts in Organic Reactions and Energy‐Based Applications
5.1 Introduction
5.2 Metallosurfactants as Catalysts in Organic Reactions
5.2.1 Types of Reactions
5.2.2 NHC Metallosurfactant‐Catalyzed Reactions
5.2.3 Stimuli‐Responsive Metallosurfactant‐Catalyzed Reactions
5.2.4 Miscellaneous Reactions
5.3 Metallosurfactants as Catalyst in Water Oxidation
5.4 Light‐Driven Hydrogen Generation
5.5 Conclusions
References
Chapter 6 Metallosurfactants as Drug‐Delivery Vehicles
6.1 Introduction
6.2 Distinct Assemblies of Metallosurfactants in Drug Delivery
6.2.1 Metallosomes as Drug‐Delivery Agents
6.2.2 Metallosurfactants and Its Self‐Assembled Structures as Nanovectors
6.2.3 Metallosurfactant Co‐polymer‐Based Micellar Systems for Drug Delivery
6.3 Metallosurfactants as MRI Contrast Agents
6.4 Conclusion
Acknowledgments
References
Chapter 7 Metallosurfactants as Molecular Machines for the Preparation of Hybrid Silica‐Based Porous Material
7.1 Introduction
7.2 Porous Silica‐Based Materials
7.2.1 Molecular Machine
7.2.2 General Synthesis Procedure of Porous Silica Material
7.3 Different Types of Porous Silica‐Based Material
7.3.1 Copper@Surfactants‐Based Porous Material
7.3.2 Ruthenium@Surfactants‐Based Porous Material
7.3.3 Cobalt@Surfactants‐Based Porous Material
7.3.4 Iron@Surfactants‐Based Porous Material
7.3.5 Other Metallosurfactant‐Based Porous Material
7.4 Future Perspectives
7.5 Conclusion
References
Chapter 8 Metallosurfactants as Non‐viral Vectors in Transfection
8.1 Introduction
8.2 Metallosurfactant Monomers
8.3 Metallomicelles
8.4 Metalloliposomes (Metallosomes)
8.5 Future Perspectives
Acknowledgments
References
Chapter 9 Metallosurfactants as Nanoreactors for Nanoparticle Synthesis
9.1 Introduction
9.2 Metallosurfactants as Reactors for Nanoparticle Synthesis
9.2.1 Colloidal Synthesis
9.2.2 Thermal Decomposition
9.2.3 Biphasic Redox Reaction
9.3 Future Perspective
9.4 Conclusion
Acknowledgments
References
Chapter 10 Metallosurfactants and Their Biological Attributes: Anticancer and Antimicrobial Properties
10.1 Introduction
10.2 Antimicrobial Activity
10.2.1 Metallosurfactants Effective against Bacteria
10.2.2 Metallosurfactants Effective Against Fungus
10.3 Anticancer Activity
10.3.1 Metallosurfactants Effective Against Breast Cancer
10.3.2 Metallosurfactants Effective Against Lung Cancer
10.4 Conclusion and Future Challenges
References
Chapter 11 Metallosurfactants as Carbon Monoxide‐Releasing Molecules
11.1 Why CO?
11.2 How to Deliver CO?
11.3 CO‐releasing Metallosurfactants
11.3.1 Synthesis of Molybdenum‐Based CORMs
11.3.2 Properties of Mixed CORAs Constituted by Molybdenum‐Based Metallosurfactants and Phospholipids
11.4 Conclusions
Acknowledgments
References
Chapter 12 Supramolecular Metal‐Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self‐Assembling Behavior and Practical Applications
12.1 Introduction
12.2 Structure, Properties, and Biomedical Application of Metallosurfactants
12.3 Amphiphilic System Based on Metallosurfactants and Macrocycles
12.4 Nanocomposites Based on Amphiphilic Resorcinarenes and Metal Nanoparticles
12.5 Conclusions
Acknowledgments
References
Chapter 13 Metallosurfactants in Nanoscale Molecular Containers as Sensors
13.1 Introduction
13.1.1 Metallosurfactants
13.2 Metallosurfactants as Nanosized Containers for Self‐assembled Molecular Devices
13.3 Surfactant Aggregates in Chemical Detection
13.4 Self‐Assembled Moieties as Fluorescent Sensors
13.5 Metallosurfactants and Detection Protocol
13.6 Conclusions
Acknowledgments
References
Index
EULA