This book presents an overview of polymer nanocomposites for use in various high-temperature applications. Specifically, it focuses on the structure and physical properties of nanocomposites based on heterocyclic matrices derived from nitrile monomers such as cyanate esters or phthalonitriles. Due to increasing interest in new heat-resistant, lightweight materials for use in extreme conditions, such as in aeronautics, microelectronics, and various industrial machinery, the high thermal stability of heterocyclic polymer networks, in particular, has attracted much attention from materials researchers and engineers. Featuring a comprehensive review of the most recent advances in research on the structure and physical properties of these promising high-temperature polymer nanocomposites, this book will be of particular interest to materials scientists and engineers working throughout the fields of aeronautical and microelectronic engineering. In general, this book is intended for use by researchers of composite materials and specialists engaged in material selection for work in extreme conditions; for students specializing in materials science; for polymer physicists, and for university libraries.
Author(s): Vladimir A. Bershtein, Pavel N. Yakushev
Series: Springer Series in Materials Science, 334
Publisher: Springer
Year: 2023
Language: English
Pages: 183
City: Cham
Preface
Contents
Abbreviations
1 Introduction. About Heat-Resistant Polymer Thermosets Used as Matrices for Nanocomposites
References
Part I Recent Advances in Studying Cyanate Ester Resin-Based Nanocomposites
2 CER/POSS Nanocomposites
2.1 Structure of the Nanocomposites Derived from Dicyanate Ester of Bisphenol E (DCBE) Monomer and PT-30 Oligomer
2.2 Far-Infrared Spectra (Matrix Dynamics)
2.3 Glass Transition, Dynamic Mechanical Analysis
2.4 Creep Rate Spectra
2.5 Thermal Stability
2.6 Influence of Variation in the Chemical Structure of the Monomer on the Properties of the CER/POSS Nanocomposites
References
3 CER/Montmorillonite Nanocomposites
3.1 About 2D MMT Nanofiller
3.2 Structure
3.3 Far-infrared Spectra (Matrix Dynamics)
3.4 Dynamic Mechanical Analysis, Glass Transition
3.5 Creep Rate Spectra
3.6 Thermal Stability
3.7 Anomalous Composition and Properties of Micron Subsurface Layer in the CER-Based Nanocomposites
References
4 Nano- and Subnanocomposites with Silica Units Introduced by a Sol–gel Method
4.1 Structure
4.2 Matrix Dynamics, Dynamic Mechanical and Thermal Analyses, Glass Transition
4.3 The Nature of the Exceptional Impact of Ultra-Low Silica Contents on the Properties of CER-Based Subnanocomposites
References
5 Other CER-Based Nanocomposites
5.1 Nanocomposites with Mesoporous Silica Particles: Materials with Low Dielectric Constant
5.2 Nanocomposites with Carbon Nanofillers (Graphene, Nanotubes)
5.3 Nanocomposites with the Unzipped Multi-walled Carbon Nanotubes
References
Part II Recent Advances in Studying Phthalonitrile Nanocomposites
6 Phthalonitrile Composites with POSS Nanoparticles
6.1 Synthesis and Spectroscopic Control of Molecular Structure and Mobility
6.2 Nanostructure
6.3 Glass Transition and Dynamic Mechanical/Thermal Behavior
References
7 Phthalonitrile/Montmorillonite Nanocomposites
7.1 Structure
7.2 Dynamic Mechanical Analysis
7.3 Thermal Stability
References
8 Phthalonitrile/Metal Oxide Nanocomposites
8.1 Phthalonitrile/Alumina Nanocomposites
8.2 Phthalonitrile/Titania Nanocomposites
8.3 Phthalonitrile/ZnO Nanocomposites
References
9 Other Types of Phthalonitrile Nanocomposites
9.1 Phthalonitrile/Silicon Nitride Nanocomposites
9.2 Phthalonitrile/Boron Nitride Nanocomposites
9.3 Phthalonitrile/MAX Phase Ceramics Nanocomposites
9.4 MXene (Ti3C2(OH)2) Nanosheet-Reinforced Phthalonitrile Nanocomposites
9.5 Phthalonitrile/Tungsten Nanocomposites
9.6 Phthalonitrile/Graphite Nanoplatelets Nanocomposites
9.7 About the Origin of Super-Heat Resistance of Phthalonitrile Nanocomposites
References
