Comprehensive Organometallic Chemistry, Fifteen Volume Set is the market-leading resource covering all areas of this critical sub-discipline of chemistry. Divided into 15 clear sections, it provides expert coverage of the synthesis, structures, bonding and reactivity of all organometallic compounds, including the mechanisms of the reactions. Applications of organometallic chemistry, such as the role of these compounds as reagents and catalysts for organometallic transformations, and their participation in bioorganometallic chemistry, is then covered. This is a vibrant area, as illustrated by the fact that the 2001, 2005 and 2010 Nobel prizes in Chemistry are all concerned with organometallic chemistry. This new edition will therefore again provide an invaluable and efficient learning resource for all researchers and educators looking for up-to-date analysis of a particular aspect of organometallic chemistry.
Author(s): Gerard Parkin, Karsten Meyer, Dermot O'Hare
Publisher: Elsevier
Year: 2022
Language: English
Pages: 418
Cover
Half Title
Comprehensive Organometallic Chemistry IV. Volume 9: Groups 11 to 13
Copyright
Contents of Volume 9
Editor Biographies
Contributors to Volume 9
Preface
9.01 Organometallic Complexes of Copper
9.01.1. Introduction
9.01.2. Organometallic Cu(I) compounds
9.01.2.1. Organocuprate(I) complexes
9.01.2.2. Carbene-Cu(I) complexes
9.01.3. Organometallic Cu(II) compounds
9.01.3.1. Isolated organocopper(II) species
9.01.3.2. Organocopper(II) species in catalysis
9.01.4. Organometallic Cu(III) compounds
9.01.4.1. Trifluoromethyl ligands in Cu(III) complexes
9.01.4.2. N-confused porphyrins (NCPs) and carbaporphyrins
9.01.4.3. Aryl-triazamacrocyclic aryl-X and aryl-H ligands
9.01.4.4. Other aryl-containing scaffolds
9.01.4.5. Cu(III) intermediate species in catalysis
9.01.4.5.1. Ullmann-type C-heteroatom couplings
9.01.4.5.2. Cu(III) species involved in Hurtley, Stephens-Castro and Csp3-Csp3 C-C couplings
9.01.4.5.3. Photocatalyzed trifluromethylation of C-X and CH bonds
9.01.4.5.4. Organocopper(III) intermediate species in CH functionalization processes
9.01.5. Conclusions
Acknowledgment
References
9.02 Silver Organometallics
9.02.1. Introduction
9.02.2. Silver(I) organometallics
9.02.2.1. Silver complexes with alkyl, alkene, arene, aryl and related ligands
9.02.2.1.1. Introduction
9.02.2.1.2. Silver arene and aryl complexes
9.02.2.1.3. Silver alkene complexes
9.02.2.1.4. Silver alkyl complexes
9.02.2.2. Silver-carbene complexes
9.02.2.2.1. Introduction
9.02.2.2.2. Novel carbenes as ligands toward silver
9.02.2.2.3. Polynuclear complex featuring halide bridges and/or argentophilic interactions
9.02.2.2.4. Macrocyclic/cage complexes
9.02.2.3. Silver complexes with other neutral carbon ligands
9.02.2.3.1. Silver isocyanide complexes
9.02.2.3.2. Silver carbonyl complexes
9.02.2.4. Alkynyl complexes of silver
9.02.2.4.1. Extended polymeric structures
9.02.2.4.2. High-nuclearity clusters
9.02.2.4.3. Miscellaneous coordination of alkynyl moieties
9.02.3. Silver(III) organometallics
9.02.3.1. Introduction
9.02.3.2. Silver(III) complexes with porphyrinoid ligands
9.02.3.3. Silver(III) complexes with other organometallic ligands
9.02.4. Summary and outlook
References
9.03 Zinc, Cadmium and Mercury
Nomenclature
9.03.1. Introduction and scope
9.03.2. Cp-M(II) complexes (M=group 12 metals)
9.03.3. NHC-M(II) complexes (M=group 12 metals)
9.03.4. Group 12 metal hydride complexes
9.03.5. Group 12 metal alkyl peroxides by O2 insertion into MC bonds
9.03.6. Low-oxidation state group 12 metal-metal bonded compounds
9.03.7. Summary
Acknowledgment
References
9.04 Recent Development in the Solution-State Chemistry of Boranes and Diboranes
Abbreviations
9.04.1. Introduction
9.04.2. Synthetic methods for the preparation of triaryl boranes
9.04.3. Organic diboranes(4) [(alkyl/aryl)4B2]
9.04.3.1. Historical background
9.04.3.2. Synthesis of organodiboranes(4)
9.04.4. Boron-boron multiple bonds
9.04.4.1. Diborenes
9.04.4.2. Diborynes
9.04.5. Hydroboration reactions
9.04.5.1. Main-group catalyzed hydroborations
9.04.5.2. Uncatalyzed hydroborations using bis(pentafluorophenyl)borane [HB(C6F5)2]
9.04.6. Carboboration reactions
9.04.6.1. 1,1-Carboboration
9.04.6.2. 1,2-Carboboration
9.04.7. Cationic boron containing compounds
9.04.7.1. Borinium cations
9.04.7.2. Borenium cations
9.04.7.3. Boronium cations
9.04.8. Boryl anions
9.04.9. Borate weakly coordinating anions
9.04.10. Boron radicals
9.04.10.1. Anionic boron radicals
9.04.10.2. Neutral boron radicals
9.04.10.3. Cationic boron radicals
9.04.11. Frontiers
9.04.11.1. Main-group catalysis
9.04.11.2. Functional polymers
9.04.12. Conclusions
References
9.05 Polyhedral Boranes and Carboranes
9.05.1. Introduction
9.05.2. Polyhedral carboranes
9.05.2.1. Literature reviews on chemistry of some carborane derivatives
9.05.2.2. Applications of carboranes in medicine
9.05.2.3. Carborane based luminescent materials
9.05.2.4. Carboranes as weakly coordinating anions
9.05.2.5. Functional group assisted B-H activation of carboranes by transition metal complexes
9.05.2.5.1. B-H activation assisted by phosphorus-containing substituents
9.05.2.5.2. B-H activation assisted by nitrogen-containing substituents
9.05.2.5.3. B-H activation assisted by oxygen-containing substituents
9.05.2.5.4. B-H activation assisted by sulfur-containing substituents
9.05.3. Polyhedral boranes
9.05.3.1. closo-Dodecaborate anion [B12H12]2-
9.05.3.1.1. General aspects. Halogen derivatives
9.05.3.1.2. Derivatives with BO bond
9.05.3.1.3. Derivatives with BS bonds
9.05.3.1.4. Derivatives with BN bonds
9.05.3.1.5. Derivatives with BP bonds
9.05.3.1.6. Derivatives with BC bonds
9.05.3.2. closo-Undecaborate anion [B11H11]2-
9.05.3.3. closo-Decaborate anion [B10H10]2-
9.05.3.3.1. General aspects. Halogen derivatives
9.05.3.3.2. Derivatives with BO bonds
9.05.3.3.3. Derivatives with BS bonds
9.05.3.3.4. Derivatives with BN bonds
9.05.3.3.5. Derivatives with BC bonds
9.05.3.4. closo-Nonaborate anion [B9H9]2-
9.05.3.5. closo-Octaborate anion [B8H8]2-
9.05.3.6. closo-Heptaborate anion [B7H8]2-
9.05.3.7. closo-Hexaborate anion [B6H6]2-
9.05.4. Conclusions
References
9.06 Polyhedral Metallaboranes and Metallacarboranes
Nomenclature
9.06.1. Introduction
9.06.2. Metallaborane clusters
9.06.2.1. Metallaborane single cage clusters
9.06.2.1.1. Metallaborane clusters of group 4 (Table 1)
9.06.2.1.2. Metallaborane clusters of group 5 (Table 2)
9.06.2.1.3. Metallaborane clusters of group 6 (Table 3)
9.06.2.1.4. Metallaborane clusters of group 7 (Table 4)
9.06.2.1.5. Metallaborane clusters of group 8 (Table 5)
9.06.2.1.6. Metallaborane clusters of group 9 (Table 6)
9.06.2.1.7. Metallaborane clusters of group 10 (Table 7)
9.06.2.2. Metallaborane fused clusters (Table 8)
9.06.3. Metallacarborane clusters
9.06.3.1. Metallacarborane clusters of group 4 (Table 9)
9.06.3.2. Metallacarborane clusters of group 5 (Table 10)
9.06.3.3. Metallacarborane clusters of group 6 (Table 11)
9.06.3.4. Metallacarborane clusters of group 7 (Table 12)
9.06.3.5. Metallacarborane clusters of group 8 (Table 13)
9.06.3.6. Metallacarborane clusters of group 9 (Table 14)
9.06.3.7. Metallacarborane clusters of group 10 (Table 15)
9.06.3.8. Metallacarborane clusters of f-block elements (Table 16)
9.06.4. Supra-icosahedral metallaborane and metallacarborane clusters (Table 17)
Acknowledgment
References
9.07 Gallium, Indium, and Thallium
9.07.1. Introduction and scope
9.07.2. Boron-based ligands
9.07.3. Carbon-based ligands
9.07.3.1. σ Ligands
9.07.3.1.1. Carbenes
9.07.3.1.2. Alkyl substituents
9.07.3.1.3. Aryl substituents
9.07.3.2. π Ligands
9.07.3.2.1. Arene ligands
9.07.3.2.2. Cyclopentadienyl ligands
9.07.3.3. Unsaturated group 13 metal-containing heterocycles
9.07.4. Heavier group 14 element-based ligands
9.07.5. Nitrogen-based ligands
9.07.5.1. Neutral donor ligands
9.07.5.2. Hydrazide ligands
9.07.5.3. Amide ligands
9.07.5.4. Amidinate and guanidinate ligands
9.07.5.5. α-Diimine ligands
9.07.5.6. β-Diketiminate ligands
9.07.5.7. Other nitrogen-based ligands
9.07.6. Heavier group 15 element-based ligands
9.07.7. Chalcogen-based ligands
9.07.8. Conclusions
Acknowledgment
References
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