Catalysis: Volume 33

This document was uploaded by one of our users. The uploader already confirmed that they had the permission to publish it. If you are author/publisher or own the copyright of this documents, please report to us by using this DMCA report form.

Simply click on the Download Book button.

Yes, Book downloads on Ebookily are 100% Free.

Sometimes the book is free on Amazon As well, so go ahead and hit "Search on Amazon"

This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight application of 2D materials in biomass conversion catalysis, plasmonic photocatalysis, catalytic demonstration of mesoporosity in the hierarchical zeolite and the effect of surface phase oxides on supported metals and catalysis. Looking to the future a chapter on ab initio machine learning for accelerating catalytic materials discovery is included. Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. Other chapters with an industrial perspective include heterogeneous and homogeneous catalytic routes for vinyl acetate synthesis, catalysis for production of jet fuel from renewable sources by HDO/HDC and microwave-assisted catalysis for fuel conversion. Chemical reactions in ball mills is also explored. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.

Author(s): James Spivey, Yi-Fan Han, Dushyant Shekhawat
Edition: 1
Publisher: Royal Society of Chemistry
Year: 2021

Language: English
Pages: 493
City: London

Cover
Preface
Editor biographies
Author biographies
Contents
Microwave-assisted heterogeneous catalysis
1 Introduction
2 Fundamentals of microwave heating
3 Microwave-assisted heterogeneous catalytic applications
4 Microwave reactor design for heterogeneous catalytic reactions
5 Challenges in microwave-assisted heterogeneous catalysis
6 Numerical modeling for microwave-assisted heterogeneous catalysis
7 Conclusion
Disclaimer
Acknowledgements
References
Plasmonic Photocatalysis
1 Introduction
2 Advantages of plasmonic photocatalysis
3 LSPR-mediated enhancement pathways
4 LSPR-mediated photocatalytic mechanism
5 Computational methods to understand and predict the plasmonic photocatalytic effect
6 Future outlook and challenges
Acknowledgements
References
Catalytic routes and mechanisms for vinyl acetate synthesis
1 Introduction
2 Historical VA synthesis methods
3 VA synthesis via heterogeneous oxidative acetoxylation of ethylene
4 Conclusion
Acknowledgements
References
Precise composition/kinetic characterization of solid catalysts using temporal analysis of products
1 Introduction
2 Comparative features of different kinetic devices
3 Experimental formats
4 Theoretical tools
5 Selected examples of TAP experiments probing composition/kinetics
6 Conclusions
Acknowledgements
References
The effect of surface phase oxides on the properties of supported metals and catalysis
1 Introduction
2 Brief overview of parameters involved in the catalytic performance of metal-supported catalysts
3 Surface properties of SPO compared with other oxide structures
4 SPOs as hierarchical metal support catalysts
5 Effect of SPOs on MSIs and SMSIs
6 Synergistic catalytic effect induced by SPOs
7 Conclusions
8 Future prospects and opportunities
Acknowledgements
References
Catalysis for production of jet fuel from renewable sources by hydrodeoxygenation and hydrocracking
1 Introduction
2 Bio-oil composition and properties
3 Jet fuel composition and specifications
4 Bio-oil hydrotreatment
5 Conclusions
6 Future prospects
References
Comprehending the application of 2D materials in biomass conversion catalysis
1 Introduction
2 Graphene and graphene derived materials for biomass conversion
3 Transition metal dichalcogenides as catalysts for biomass conversion
4 Other 2D catalytic materials for biomass conversion and future outlook
5 Conclusion
Acknowledgements
References
Catalytic demonstration of mesoporosity in hierarchical zeolites
1 Defining hierarchically nanoporous zeolites
2 Synthetic strategies for hierarchical zeolites
3 Catalytic demonstration of hierarchical zeolites
4 Conclusions
Abbreviations
References
Titanate nanotubes produced by hydrothermal synthesis: study of catalytic and adsorptive properties
1 Hydrothermal preparation of titanate nanotubes
2 Structural properties and surface functionalization
3 Adsorptive properties
4 Mode of action and applications
5 Conclusions and outlook
Abbreviations
Acknowledgements
References
Catalytic reactions in ball mills
1 Mechanical forces and chemical reactions
2 Specific effects of ball milling for chemical reactions
3 Types of ball mills and their scalability
4 Mechanochemistry of catalyst synthesis
5 Catalytic reactions in ball mills
6 In situ analysis of milling effects
7 Concluding remarks and outlook
References
Ab initio machine learning for accelerating catalytic materials discovery
1 Introduction
2 A general picture of machine learning in the chemical sciences
3 Machine learning in heterogeneous catalytic materials discovery
4 A brief introduction to machine learning in homogeneous and enzyme catalytic materials discovery
5 Challenges and opportunities
6 Conclusions
Acknowledgements
References
In-situ studies of catalytic reactions over well-defined model catalysts
1 Introduction
2 Structure and dynamics of surface adsorbates: from UHV to condensed layers
3 CO oxidation
4 CO reduction
5 Outlook
Acknowledgements
References
Electrocatalysts
1 Introduction
2 Applications of electrocatalysts
3 Summary and outlook
References