Page 1
Titles
REVIEWS In
MINERALOGY
Volume 98
AMPHIBOLES:
PETROLOGY and EXPERIMENTAL
DAVID R. VEBLEN & PAUL H. RIBBE, Editors
The Authors
Series Editor
MINERALOGICAL SOCIETY OF AMERICA
Page 1
Titles
COPYRIGHT
1982
PRINTED BY
REVIEHS IN MINERALOGY
Page 1
Titles
AMPHIBOLES: Petrology and
TABLE of CONTENTS
Chapter 1
PHASE RELATIONS of METAMORPHIC AMPHIBOLES:
NATURAL OCCURRENCE and THEORY
Peter Robinson, Frank S. Spear, John C. Schumacher,
lo Laird, Cornelis Klein, Bernard W. Evans & Barry L. Doolan
.............
Chemical limits 6
Crystal-chemical limits 6
& DOOLAN) 9
(ROBINSON, DOOLAN & SCHUMACHER) 22
Control by M4 site in monoclinic and orthorhombic amphiboles 45
(ROBINSON)
Coupled M4-M2 relation (ROBINSON) 47
Tetrahedral Al and A-occupancy (ROBINSON) 48
Miscibility gaps and substitution mechanisms (SPEAR) 49
Chemographic relations (SPEAR, ROBINSON & SCHUMACHER) 50
Exsolution lamellae (ROBINSON) 57
Chemographic relations (ROBINSON & SCHUMACHER) 61
Exsolution lamellae (ROBINSON) 62
Page 2
Titles
Chemographic relations (ROBINSON & SCHUMACHER) 63
Exsolution lamellae (ROBINSON) 63
Chemographic relations (SPEAR) 66
Exsolution lamellae (ROBINSON) 68
& SPEAR) 76
Calcic amphibole
Calcic amphibole
Page 3
Titles
Chapter 2
EXPERIMENTAL STUDIES OF AMPHIBOLE STABILITY
Page 4
Titles
. . . . . . . . .. ..
.. .
. . . .. . .
. . . . . .. . .
Page 5
Titles
Chapter 3
AMPHIBOLES in the IGNEOUS ENVIRONMENT
David R. Wones & M. Charles Gilbert
ix
Page 6
Page 1
Titles
REVIEWS in MINERALOGY
Volume 9B.
AMPHIBOLES:
PETROLOGY and EXPERIMENTAL PHASE RELATION~
FOREWORD
iii
REV009Bpreface.pdf
Page 1
Titles
PREFACE and ACKNOWLEDGMENTS
Page 1
Titles
Chapter 1
PHASE RELATIONS of METAMORPHIC AMPHIBOLES:
NATURAL OCCURRENCE and THEORY
Peter Robinson, Frank S. Spear, John C. Schumacher,
[o Laird, Cornelis Klein, Bernard W. Evans & Barry L. Doolan
Page 2
Page 3
Page 4
Page 5
Page 6
Page 7
Tables
Table 1
Page 8
Page 9
Page 10
Titles
~~IM
~I~
"I Nlo ~ ~ ~ ° 1° ~ ~I~ ~I~
Tables
Table 1
Page 11
Titles
""
~
U
11
'"
l" 11)
::l
"" "
...
~]
!S~
~
...
I""
'"
g,~
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Ol
g:g
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... .,.,
Page 12
Page 13
Page 14
Titles
~ w~
AI3+
~r!"o~~,?
o
~
.~'_Lill~
14
Page 15
Page 16
Page 17
Titles
50
4·5
4·0
3-5
3·0
(M 1-2-3)
2·5
2-0
15
(Ml-2-3)
Mg
1·0
0-5
o
(Ml-2-3)
17
Tables
Table 1
Table 2
Page 18
Page 19
Titles
Mg
on fh\P.p.", n
(A)
1-'
o
0-2
0-4
(A)
0-6
0·8
0·2 0
1·0
II
(A) :
r',
n l L
'"
~
Tables
Table 1
Page 20
Page 21
Titles
""
21
Tables
Table 1
Page 22
Page 23
Titles
E~~;~~~~~ite ,.
NCFM
A
NCFM
\
A
23
Page 24
Titles
"s"
Page 25
Titles
/
..
l
A
B
Page 26
Page 27
Titles
"eFM'1
Page 28
Titles
\
20
20
\
Glaucophane / / o. \ r .... CFM
__ N J / / ••.•• y 0
I:
Ideal Gedrite
Glaucophane ,r \0" •• /' ' / • • / '
--N.
Eckermannite
60
Richterite
28
Page 29
Titles
A
N/----
/
Page 30
Titles
"N"
Page 31
Titles
s
o
80
31
s
-20
Page 32
Titles
!,,~,~
Page 33
Titles
\
A
20
Cummingtonite
40
Gedrite
\" /
. /
'ic!: ...
LoP,''',
'-, ~ 1-_ \ - .. _ ... "~FM
7' ..... 9 .\ l\ \
• Actinolite
t I Richterite
Eckermannite
Page 34
Titles
1"A"]
Page 35
Titles
i
Tschermokif
Pargosite
,
--:~1-2·0
,. ,
•
1
,-----,---,-------,- 2·5
I .'
I
I
,
, I
Glaucophone ;(:
Riebeckite .!/;!!.,,_._
I '" '
" ,
I, •
I ,·0·2
~_-~~-~~~_-: ~-~--~_----1
-1.0 -0·1 0 0·3 0·7 1·0
A/2R3+ __ ~
Eckermonnite
Page 36
Page 37
Titles
2Ti4+
2Ti4+
Page 38
Titles
2Ti4+
Page 39
Titles
~
Page 40
Titles
A
16
14
12
R3+ __,.
02 04 06 08 10
o
1·8
16
20
14
B
I
I ..
1·4
0·6 0·8 1·0 1·2
0-4
'" .
0·2
o
0·2
o
0·8
0·9
0·1
<:t 0·7
c 0.6
o
z 0.5
~ 0-4
u 0.3
40
Tables
Table 1
Page 41
Titles
c
,
I
\
,
"
2·0 n--':
o
0·2
~
..
...
o
u 02
o
, ,
..
, ,
..
02
o
Page 42
Page 43
Page 44
Page 45
Page 46
REV009BC001_p47-92.pdf
Page 1
Page 2
Titles
Tetrahedral Al and A- occupancy.
Page 3
Page 4
Page 5
Tables
Table 1
Page 6
Titles
52
Tables
Table 1
Page 7
Titles
, ..
Page 8
Page 9
Tables
Table 1
Page 10
Page 11
Tables
Table 1
Page 12
Page 13
Page 14
Page 15
Page 16
Tables
Table 1
Page 17
Tables
Table 1
Page 18
Titles
.s
o 0
B
o
c
\ '\n'l, 0 - !
o
Page 19
Page 20
Page 21
Titles
-
«
Tables
Table 1
Table 2
Table 3
Page 22
Titles
u
r=-
0"<><>,, 8<>.
~
u
;:
o
Tables
Table 1
Page 23
Page 24
Page 25
Page 26
Tables
Table 1
Table 2
Table 3
Table 4
Page 27
Titles
to
f ' : .: 'f.l:f
w
oJ)
-c
73
Tables
Table 1
Table 2
Table 3
Page 28
Page 29
Titles
x
x
Page 30
Page 31
Page 32
Tables
Table 1
Page 33
Titles
c
Tables
Table 1
Page 34
Page 35
Page 36
Page 37
Page 38
Tables
Table 1
Page 39
Titles
tOl
l
Page 40
Page 41
Titles
w
U 0 ~ , , , , j~
~r ~1~~:
'"
~
..
87
Tables
Table 1
Table 2
Table 3
Page 42
Page 43
Page 44
Titles
;:;!:~tr;:1!n~xi~~~, 5~9!4~~ 88.8 .tomic
"""",,'00 ,,,,,)! '
cummingtonite
grunerite
ferrodolomite quartz
grunerite calcite
siderite
quartz
grunerite
rrrinnesotaite
gr'unerite
quartz
90
Tables
Table 1
Table 2
Page 45
Page 46
Titles
A
c
ferrodbmomite quartz
REV009BC001_p93-138.pdf
Page 1
Titles
D
grunerite calcite
Tables
Table 1
Page 2
Page 3
Tables
Table 1
Page 4
Page 5
Titles
B
.
Page 6
Titles
A
Tables
Table 1
Page 7
Titles
I
~i!!\
--~--.-+
~ -~------
~---
Page 8
Titles
Calcic amphibole.
Tables
Table 1
Page 9
Page 10
Page 11
Titles
. .
... ~,~ ...
.
Si
Tables
Table 1
Table 2
Page 12
Page 13
Titles
~
?E .. '"
~ .. .... : .
-t, :
.~
' ..
.;, .
Page 14
Tables
Table 1
Page 15
Tables
Table 1
Page 16
Page 17
Page 18
Page 19
Page 20
Page 21
Page 22
Page 23
Page 24
Page 25
Page 26
Tables
Table 1
Page 27
Page 28
Titles
'"
.=
~:
' ..
,
\ ..
i "'
i "'
i .~
\
,
....
I
w
o
2
~ ~
°1°
0°
'"
'"
Tables
Table 1
Page 29
Titles
Fe"
,
G l 4 & • 10 i2 14 16---18 20-222426 28 30 32 34 j8
Si+AI
I~
...
14
'C~l·
" ,'.
:: .... ~ »»
• ' ... .,. C'"
..
-, a ,
b)
I""
0)
c)
121
Page 30
Tables
Table 1
Page 31
Page 32
Titles
124
Page 33
Titles
-:
c.
Page 34
Page 35
Titles
cso
127
Page 36
Titles
[AMP] [AMP] [ENV]
Page 37
Page 38
Tables
Table 1
Table 2
Page 39
Titles
'"
o
;:01
o
"
131
Page 40
Tables
Table 1
Page 41
Page 42
Titles
1:1
~I
,
I
I
__,.., "i<= \ I {
Page 43
Page 44
Titles
o
o
0. til ~'"
. '" '"
0~ & 0 ""
~
0.'
~,2'~"J ...
1.0,--;:--,----,---,.---,.--------,
'"
~
~
'"
/
rJ'V"'O CO.,. m
(\.['-.1""'-0
r AF 1
136
Page 45
Titles
"
Tables
Table 1
Page 46
Tables
Table 1
REV009BC001_p139-184.pdf
Page 1
Page 2
Page 3
Page 4
Titles
[nG] [~] [~]
Page 5
Page 6
Titles
NazO
( F~~+)
CaO
144
Tables
Table 1
Page 7
Page 8
Titles
:" ~
~~~~
.~
\ ',,, ,
... '~~
"'.
Tables
Table 1
Page 9
Page 10
Page 11
Titles
i I I j__
I
i
I I I
I
Page 12
Titles
(Fe.Mg)
Co
(Fe.Mg)
Co
150
Page 13
Titles
--
r .,.".' 0. «)_...-
_' crdlf!Y ......
. --
Tables
Table 1
Page 14
Page 15
Titles
o
o
o
o
• "J~/
• '--ei----_:;,-'
-o------6',?
t
r--- ---
I
o
153
Tables
Table 1
Table 2
Page 16
Page 17
Titles
__ -
Tables
Table 1
Page 18
Page 19
Titles
....
(31)
Page 20
Titles
b)
0)
Tables
Table 1
Page 21
Page 22
Page 23
Page 24
Page 25
Page 26
Titles
CoO
Ca-O,53SNa
AI-2,077Na
Mg
Fe
Fe'
@
Anlh-=
164
Page 27
Page 28
Page 29
Titles
Low-grade assemb'Zages and orthoamphiboZe-forming reactions. Amphibolites
Page 30
Page 31
Titles
« - u
169
Page 32
Page 33
Page 34
Titles
40
-20
172
Page 35
Titles
A
M
F
(4
Page 36
Page 37
Titles
Na IAI GED 1
175
Page 38
Titles
B05
o
«
Tschermokite
o
AI'·
2
3
J
o
02
04
.----._
0·6
176
Tables
Table 1
Page 39
Page 40
Titles
FeO+
__ ~ MnO
-Ti02
Page 41
Titles
FeO+MnO
MgO
FMO- TiO,
Page 42
Titles
SilL" Alp,. Fe,O,+2TiO;-Na,O
FeO'MnO
MgO
MgO
FeO'MnO
Page 43
Page 44
Page 45
Page 46
Tables
Table 1
REV009BC001_p185-227.pdf
Page 1
Titles
c
Page 2
Page 3
Titles
c
o.
AUG HBLD
Page 4
Titles
c
o.
AUG HBLD
Page 5
Page 6
Page 7
Titles
•
I
I
Page 8
Page 9
Page 10
Page 11
Titles
10 \
5
o
ORTHOPYROXENE
195
Tables
Table 1
Page 12
Titles
o
\
o
o
:;;;: ......
o
tf
w
u
o
c
L/
o
tf
::>0
1/
CD
1%
Tables
Table 1
Page 13
Page 14
Page 15
Titles
CD
'""." '"" ~
Page 16
Page 17
Titles
F
Page 18
Titles
c
b.
o.
A
Orthopyroxene
FM
Page 19
Titles
Orthopyroxen
FM
A
c.
CJ-
Page 20
Titles
Garnet
50
Page 21
Page 22
Page 23
Page 24
Page 25
Page 26
Page 27
Titles
__ ,
211
Page 28
Titles
212
Page 29
Titles
--'
--'
213
Page 30
Titles
__ '
__ '
214
Page 31
Titles
215
Page 32
Titles
__ ,
216
Page 33
Titles
217
Page 34
Titles
__ '
218
Page 35
Titles
219
Page 36
Titles
--'
220
Page 37
Titles
221
Page 38
Titles
222
Page 39
Titles
--'
--'
--'
223
Page 40
Titles
224
Page 41
Titles
225
Page 42
Titles
226
Page 43
Titles
Wolff, R. A. (1978) Ultrcmc.fic Lenses in the giddZe O;rdop:,c~~c:n Partx-idae ?orma-;ion~ Bronson
Zajac, 1. S. (1974) The Stratigraphy and ,4Jineralogy of the Sokoman Formation in the Knob Lake
227
Page 44
Page 1
Titles
Chapter 2
EXPERIMENTAL STUDIES OF AMPHIBOLE STABILITY
M. Charles Gilbert, Rosalind T. Helz, Robert K. Popp & Frank S. Spear *
*
Page 2
Page 3
Page 4
Titles
L,
800
700
600
LL I ;;: 'I;;:
f-Iw 1-,0
1 E '~: ~'
-;:----p----r-
1:1 /'1'
:1 /:
II / 1
I / 1
II s/ I;;:
I, ;;/ I [i}
I I~ / 1
~/I ILL / I
:;_ 1<1;/ 1
1-1 I / I
I I / I
20
10
p
kbar
')
,
, .
"
"
800
700
600
p
kbar
232
Page 5
Page 6
Page 7
Titles
'" 3000r I~
.,.:'f
I
I :g
I
I
Tables
Table 1
Table 2
Page 8
Titles
Orthorhombic Unit Cell Parameters
I
,
m w w w ~
Mole % Fe7Si8022 (OH)2
•
~
Tables
Table 1
Table 2
Page 9
Titles
Low-temperature stability limits.
High-temperature stability limits.
Page 10
Tables
Table 1
Page 11
Titles
.,
"'''
,,-.2
..
"
o
~
I c: 1 I~~
u;
,_
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ae
.,
:2
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o
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~ ~ ~
f- u"'
..
Page 12
Page 13
Page 14
Page 15
Titles
Fe -Mg AMPHIBOLE SOLUTION SERIES
Amphss + Mt
".p
-,fd ~o
~ ~
\1> q.
\\
Amph \
+ \
V \
Page 16
Titles
700°C
......
............
'"
~
NNO .:!2..t-----
Page 17
Titles
Mg-end member (tremolite).
Page 18
Titles
Fe-end member (ferro-tremolite or ferro-actinolite) 1.
Intermediate compositions.
Page 19
Titles
(4)
1errotremoJite 'ot
+ fluid ,,'
,)8)
"
"
C ,/'
· "
· ,
· "
:8/'
."
:'
,
,
'"
Temperature in ·C
\ \ r. \\ ~,W~
Mole percenl
"',S..a,,(OH~
247
Page 20
Page 21
Titles
o
o
100
10
o
Mole percent actinolite
249
Tables
Table 1
Page 22
Titles
+01 + Otz
Mole % Ferrolremolile Mole % Ferrolremolile
END MEMBER STABILITIES: PARGASITE - HASTINGSITE SERIES
...
: ...
250
Tables
Table 1
Page 23
Page 24
Titles
Pfluid• 2000 bars
~
'"
252
Page 25
Page 26
Titles
.... ~~~.;i~~ ...
.'
,( .
....... [§]J
....
~
~
a:
o
:5
~
Page 27
Titles
.,.-
_____ }:;, g A ~-----.~-- _
~'-,.'. "" "" -
UNT ..- {, t; I:>
26
o
o
o
o
o
o
o
o
o
" \,
" /_\~~:-:~~~,~;-,? 0
. ---or ()_)-./O 0 0
85C!Y~f'?~~'~
255
Tables
Table 1
Page 28
Page 29
Titles
TABLE 2.
Summarized experimental data on edenite stability.
Ed,,+Ab = Rc,,+Di,,+Fo.
2
P(t
Tr/<~I ~I
Qz Fo
Rc •
L
800 ~g 1000
~ ~roo
. .
257
Tables
Table 1
Page 30
Tables
Table 1
Page 31
Page 32
Titles
TEMPERATURE,
1
...'
Tables
Table 1
Table 2
Page 33
Titles
Composilion (N02 Co Mg. Fe5_. Sia02210H)2)
(WM;FMQ)
(HM)
(WM) (HM)
(IW)
261
Tables
Table 1
Table 2
Page 34
Page 35
Titles
__ -
_-
en
__ --l4)------
'"
Page 36
Titles
=
~
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'"
'"
'"
o
o "
'"
Q.. ::C:s: 0
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"7 ~ ~
L__ 'qi ~ ~
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o
o
o
264
Tables
Table 1
Page 37
Page 38
Page 39
Page 40
Titles
::;
\
Page 41
Titles
., .,
~M" i:
hi I / 1/
Page 42
REV009BC002_p271-314.pdf
Page 1
Titles
/
PH20 =
271
Tables
Table 1
Page 2
Page 3
Titles
Weight per cent
T=850°C
Sil
iii
iii/iii
ii ii
273
Page 4
Tables
Table 1
Page 5
Titles
HM BUFFER
: om +pl+ cp
aJ ~i~ ",'"
. = //
orn+pl+hm+sp aqt ~",/.*
e<'-;:" f} ±Qt ±pb
e ~f'" ®~QIIl «IIIj !Ij
'" e Q'iI
.: pl'. • S
'"
:.:::
z
am +pl + i I
Q FM BUFFER
TEMPERATURE °C
275
Page 6
Titles
/
Page 7
Page 8
Page 9
Page 10
Page 11
Page 12
Titles
c;
ri
a..
df_.cl=pmo,
e.-
g! f 'M" • , .,.; •..
iJ \
I u>
,1 _______
.
T-
Page 13
Page 14
Page 15
Page 16
Tables
Table 1
Page 17
Page 18
Page 19
Titles
Table 3. ehemical analyses of andesites and one tonalite
Tables
Table 1
Table 2
Page 20
Page 21
Page 22
Page 23
Titles
~
293
Tables
Table 1
Page 24
Page 25
Page 26
Page 27
Page 28
Titles
:-- t
\ -,),
: f
. I
1
en
c::
a.
TEMPERATURE,oe
298
Tables
Table 1
Page 29
Titles
PYROLITE
.. /. '.
~
Page 30
Page 31
Page 32
Page 33
Titles
(1)
Page 34
Page 35
Titles
~!Rl
,
I=--J-:.r
~
,
iF
Page 36
Page 37
Titles
1100
900
700
T(OC)
';
o
2 4 6 8 10 12
Wt. % H20
Page 38
Page 39
Page 40
Page 41
Page 42
Titles
ci
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312
Tables
Table 1
Table 2
Page 43
Page 44
Titles
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314
REV009BC002_p315-354.pdf
Page 1
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"0 c-, '"
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316
Page 3
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°2
v
0.41
0.51
98.01
Page 4
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Page 6
Tables
Table 1
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•
322
Tables
Table 1
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0.4
0.3
Na(M,) per 23 oxygens
324
Tables
Table 1
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"',2
...
"'
329
Tables
Table 1
Table 2
Page 16
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w
** X
t *
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1
339
Tables
Table 1
Table 2
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CHAPTER 2 REFERENCES
348
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349
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350
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352
Tables
Table 1
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Sykes, N. L. (1979) 8yd:rous mi-neral- stabi~ity as a function of fluid composition: a biotite
353
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Chapter 3
AMPHIBOLES in the IGNEOUS ENVIRONMENT
David R. Wones & M. Charles Gilbert
Tables
Table 1
Table 2
Page 2
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TABLE 1.
Sources of data on the stability of amphiboles and biotites.
Mg-Ca pyroxenes
calcic plagioclases
I
I
~ calci-alkalic plagioclases
\
\
Mg pyroxenes
olivines
\ alkali-calcic plagioclases
amphiboles
I
\ alkalic plagioclase
biotites
\
I
potash feldspar
muscovite
quartz
356
Tables
Table 1
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-
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TABLE 2.
Oxygen buffer curves.
2
-5
-25
1.1
359
Tables
Table 1
Table 2
Page 6
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T,OC
Tables
Table 1
Page 7
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.1___Q_!
.... __ a
.....
T,OC
o
Page 9
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6
~\~
~
ili
ili
L
/,\:>;QZ
/;1\ .'
~'..
T-- ........
&
»:
L·A·~/M'
Page 12
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Si
Page 14
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Page 16
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/'
Tables
Table 1
Page 17
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~'r~l
Page 19
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CALCIC AMPHIBOLES
Page 21
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•
.,~
•
•
.... /.' .
•
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..,
"
\
.. :.\.
.
Tables
Table 1
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Ca <1.34
-+-t--+--+-t--+--+--t-t-+--f-·t-·I'~
-A-'-
,
.r_~~!. ,!~~!.
~---- : ~'o"o;
,
379
Tables
Table 1
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'r--------------\'"
-~,
3
2
EARLY MAGMATI C
STAGES
LA TE MAGMAT r c
Q STAGES
04------.------,-----,------,----
6
7
8
9
381
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t
T
Tables
Table 1
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CHAPTER 3 REFERENCES
/Beams , S. D. (1980) Magmatic Evolution of the Southeast Lachl-an fold belt, Australia. Ph.D.
386
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--'
387
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Noyes, H. (1978) Comparat-ive Petrochemistry of the Red Lake and Eagle Peak Plv zone, Sierra.
Ransome, F. L. (1898) Some Lava Flowe c= ::.he veetern S~ope of the si er-ea cevcda, :;~i.~i .. =orni.a,
388
Tables
Table 1
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Tuttle, O. F., and Bowen, N. L. (1958) Origin of Granite in the Light of Experi.:'nental studies
389
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390
