Advanced Polymeric Materials

Cover
Half Title
Series
Title
Copyright
Contents
Preface
List of Contributors
List of Figures
List of Tables
List of Abbreviations
1 Bisbenzoxazine–Bismaleimide Blends: Thermal Studies
1.1 Introduction
1.2 Experimental
1.2.1 Materials
1.2.2 Synthesis of Bis(3,4-Dihydro-2H-3-Phenyl-1, 3-Benzoxazinyl) Isopropane (BAB)
1.2.3 Synthesis of 2,2-Bis(4-Nitrophenoxyphenyl) Propane (DN-BPAPCNB)
1.2.4 Preparation of 2,2-Bis(4-Aminophenoxy Phenyl) Propane (DA-BPAPCNB)
1.2.5 Preparation of Bisamic Acid (BAX)
1.2.6 Preparation of 2,2-Bis[4-(4-Maleimidophenoxy Phenyl)]propane (EXBMI)
1.2.7 Blending of the Materials
1.2.8 Polymerization of the Materials
1.2.9 FTIR Studies
1.2.10 Differential Scanning Calorimetric (DSC) Studies
1.2.11 Thermogravimetric (TG) Studies
1.3 Results and Discussion
1.3.1 FTIR Studies
1.3.2 DSC Studies
1.3.3 TG and DTG Studies
1.4 Conclusions
Acknowledgements
References
2 Studies on Thermosetting Resin Blends: Bispropargyl Ether-Bismaleimide
2.1 Introduction
2.1.1 Thermosetting Resins
2.1.2 High Performance Thermosets
2.1.3 Bismaleimide
2.1.4 Acetylene-terminated Resins (ATRs)
2.1.5 Propargyl-terminated Resins (PTRs)
2.1.6 Property Enhancement in PT Resins
2.1.7 Literature
2.2 Experimental
2.2.1 Preparation of BPEBPA, BMIM, and BMIE
2.2.2 Blending of Bispropargyl Ether of Bisphenol-A with BMIM and BMIE
2.2.3 Thermal Curing of the Materials
2.2.4 Methods
2.2.4.1 FTIR analysis
2.2.4.2 DSC analysis
2.2.4.3 TG analysis
2.3 Results and Discussion
2.3.1 FTIR Studies
2.3.2 DSC Studies
2.3.3 TG and DTG Studies
2.4 Conclusions
Acknowledgements
References
3 Synthesis, Characterization, Magnetic, Thermal and Electrochemical Studies of Oxovanadium(IV) Complex of 2-thiophenecarba Benzhydrazone
3.1 Introduction
3.2 Experimental
3.2.1 Physical Measurements
3.2.2 Materials
3.2.3 Synthesis of Ligand
3.2.3.1 Synthesis of 2-thiophenecarba benzhydrazone
3.2.4 Synthesis of Complex
3.2.4.1 Preparation of 2-thiophenecarba benzhydrazonato oxovanadium(IV)
3.3 Results and Discussion
3.3.1 Characterization of the Ligand (2-Thiophenecarba Benzhydrazone)
3.3.2 Characterization of the Complex
3.3.3 Proposed Structure of the Complex
3.4 Conclusion
Acknowledgements
References
4 Sorption and Desorption Analyses of Sorbents for Oil-spill Control
4.1 Introduction
4.1.1 Pollution-prevention Application of Polymers
4.1.2 Problem of Oil Spill
4.2 Factors Affecting the Performance of Sorbents
4.3 Sorption and Desorption Kinetics
4.3.1 Sorption Kinetics
4.3.2 Desorption Models
4.3.3 Sorption-desorption Analysis of Polyurethane Foam
4.4 Conclusion
References
5 Polyhexahydrotriazines: Synthesis and Thermal Studies
5.1 Introduction
5.1.1 Polymer
5.1.2 Classification based on Thermal Behavior
5.1.3 Thermosetting Polymer
5.1.4 Thermoset Materials
5.1.4.1 Phenol formaldehyde
5.1.4.1.1 Novolacs
5.1.4.1.2 Resoles
5.1.4.2 Urea–formaldehyde resin
5.1.4.3 Melamine formaldehyde resin
5.1.4.4 Unsaturated polyester resin
5.1.4.5 Epoxy resins
5.1.4.6 Bismaleimides
5.1.4.7 Bispropargyl ethers
5.1.4.8 Cyanate ester
5.1.4.9 Triazines
5.1.4.10 Polyhexahydrotriazine
5.2 Experimental
5.2.1 Preparation of Hemiaminal Using 4,4’-Methylenedianiline (HA-MDA)
5.2.2 Thermal Curing
5.2.3 Methods
5.3 Results and Discussion
5.3.1 FTIR Studies
5.3.2 Thermal Studies
5.4 Conclusion
Acknowledgements
References
6 Influence of Cement Behavior with and without Polymer Nano Composites
6.1 Introduction
6.2 Experimental Program
6.2.1 Tests on Cement Mortar
6.3 Results
6.4 Discussions of Test Results
6.4.1 Physical Characteristics
6.4.2 Dispersion Mechanism
6.4.3 Compressive Strength
6.5 Conclusions
References
7 Effect of Structure of Diphenol on Polymerization of Bis(isoimide)
7.1 Introduction
7.1.1 High-performance Thermosetting Resin
7.1.2 Alkyd Resins
7.1.3 Amino Resins
7.1.4 Unsaturated Polyester Resins
7.1.5 Allyl Resins
7.1.6 Epoxy Resins
7.1.7 Polyurethanes
7.1.8 Silicone Resins
7.1.9 Cyanate Ester Resins
7.1.10 Phenolic Resins
7.1.10.1 Allyl functional phenols
7.1.10.2 Bisoxazoline phenols
7.1.10.3 Phenolic resins epoxy systems
7.1.11 Polyimide
7.1.11.1 Classification of polyimides
7.1.11.2 Properties of polyimide
7.1.12 Bismaleimides (BMIs)
7.1.13 Isoimides
7.1.14 Polyisoimide
7.1.15 Bis(isoimides)
7.1.16 Maleimide and Isomaleimide
7.2 Experimental
7.2.1 Materials
7.2.2 Preparation of Bis(isoimide) of 4,4’-Methylene Dianiline
7.2.3 Blending of Bisphenols with Bis(isoimide) (VS)
7.2.4 Thermal Curing
7.2.5 Fourier-transform Infrared (FTIR) Studies
7.2.6 Differential Scanning Calorimetric (DSC) Studies
7.2.7 Thermogravimetric (TG) Studies
7.3 Results and Discussion
7.3.1 Fourier-transform Infrared Studies
7.3.2 Differential Scanning Calorimetric Studies
7.3.3 TG and DTG Studies
7.4 Conclusion
Acknowledgements
References
8 Natural Fiber Based Bio-materials: A Review on Processing, Characterization and Applications
8.1 Composite Materials
8.1.1 Particle Reinforced Composite
8.1.2 Fiber-reinforced Composite
8.1.2.1 Continuous fiber composite
8.1.2.2 Discontinuous fiber composite
8.1.3 Laminate Composite
8.1.4 Flake Composite
8.1.5 Hybrid Composite
8.2 Classification Based on Matrix Materials
8.2.1 Metal Matrix Composite
8.2.2 Ceramic Matrix Composite
8.2.3 Polymer Matrix Composite
8.3 Natural Fiber Reinforced Polymer Composites
8.3.1 Matrix
8.3.2 Reinforcement
8.3.3 Fabrication Methods
8.3.3.1 Hand lay-up
8.3.3.2 Compression moulding
8.3.3.3 Injection moulding
8.3.3.4 Pultrusion
8.3.3.5 Filament winding
8.3.4 Structure of Natural Fiber
8.4 Characterization
8.4.1 Mechanical Characterization
8.4.2 Thermal Characterization
8.4.3 Water Absorption Properties
8.4.4 Tribological Behavior
8.5 Application of Natural Fiber Reinforced Polymer Composite
8.6 Conclusion
References
9 Tribological Performance of Polymer Composite Materials
9.1 Introduction
9.2 Tribological Characterization Techniques for Polymer Composites
9.3 Preparation of Polymer Nanocomposites
9.4 Tribology Study of Different Polymer Nanocomposites
9.4.1 Metallic Nanoparticles-based Polymer Nanocomposites
9.4.2 Nanometal Oxide-based Polymer Nanocomposites
9.4.3 Nanoclay-based Polymer Nanocomposites
9.4.4 Carbon Nanotube-based Polymer Nanocomposites
9.4.5 Graphene-based Polymer Nanocomposites
9.4.6 Fullerenes-based Polymer Nanocomposites
9.4.7 Nanodiamonds-based Polymer Nanocomposites
9.5 Conclusion
References
10 Computational Modeling and Theoretical Strategies for the Design of Chiral Recognition Sites Using Molecular Imprinting Technology
10.1 Introduction
10.1.1 Enantiomeric Sensing System Tailored by Molecular Imprinting Technology
10.1.2 Computational Modeling
10.2 Theoretical and Computational Strategies in MIPs
10.3 Conclusions
References
11 Ultrafast Characterization 2D Semiconducting TMDC for Nanoelectronics Application
11.1 Introduction
11.2 Ultrafast Characterization Process
11.3 Ultrafast Characterization Techniques
11.3.1 Ultrafast Transient Absorption
11.3.2 Time-resolved Photo Electron Spectroscopy
11.4 Graphene
11.5 Two-Dimensional Semiconductors
11.6 Direct and Indirect Band Gaps
11.7 Transition Metal Dichalgogenide
11.8 Preparation of Transition Metal Dichalcogenides
11.8.1 Exfoliation Method for 2D Transition Metal Dichalcogenide
11.8.2 Chemical Vapor Deposition for Two-dimensional Transition Metal Dichalcogenide
11.8.3 Characterization of Transition Metal Dichalcogenide
11.8.3.1 Optical properties
11.8.3.2 Raman spectra
11.8.3.3 Photoluminescence (PL) evaluation
11.8.3.4 Electrical property
11.8.3.5 Electrical transport property
11.8.3.6 Electrical performance
11.8.4 Different Types of TMDC Materials
11.8.4.1 Ultrafast process in MoS2
11.8.4.2 Ultrafast process in WSe2
11.8.5 Application
11.8.5.1 Digital electronic devices
11.8.5.2 TMDC transistors
11.8.5.3 Optoelectronics
11.9 Conclusion
References
Index
About the Editors